Flexible nanosheets for plasmonic photocatalysis: microwave-assisted organic synthesis of Ni–NiO@Ni2CO3(OH)2 core–shell@sheet hybrid nanostructures

Abstract

Visible light-active nickel-based plasmonic photocatalysts provide a cost-effective alternative to noble metals. However, their rarity, fragility, and limited understanding pose challenges. This work presents a microwave-assisted organic synthesis of a Ni–NiO@Ni2CO3(OH)2 core–shell@sheet plasmonic photocatalyst. By employing time and power dependent synthesis, this catalyst exhibits flexible Ni2CO3(OH)2 nanosheets enveloping the Ni–NiO structure, surpassing the pristine Ni@NiO/NiCO3 core–shell counterpart. Chemical reaction mechanisms suggest that irradiation of pristine Ni–NiO/NiCO3 nano structures leads to breakage of amorphous NiCO3 to Ni2+ and CO32−, which further, in the presence of water solvent, interacts with OH− ions leading to the formation of Ni(CO3)·Ni(OH)2. With enhanced light absorption and photocatalytic properties, the resulting core–shell@sheet photocatalyst demonstrates double the hydrogen evolution reaction yield (40 μmol g−1 h−1) compared to the pristine catalyst (20 μmol g−1 h−1). The enhanced H2 yield is attributed to the flexible sheets, cross-dimensional photocatalyst structure, increased surface area for surface reactions, and higher H2 activity of Ni2CO3(OH)2. This research showcases the potential of microwave-assisted synthesis in developing flexible nanosheets with superior solar water splitting performance. --//-- This is an open access article Ekta Rani, Parisa Talebi, Terhi Pulkkinen, Vladimir Pankratov, Harishchandra Singh; Flexible nanosheets for plasmonic photocatalysis: microwave-assisted organic synthesis of Ni–NiO@Ni2CO3(OH)2 core–shell@sheet hybrid nanostructures; Nanoscale Advances Issue 24, 2023; https://pubs.rsc.org/en/content/articlelanding/2023/na/d3na00583f; DOI: DOI https://doi.org/10.1039/D3NA00583F published under the CC BY-NC licence.